Using Two Compatible Donor Polymers Boosts the Efficiency of Ternary Organic Solar Cells to 17.7%
نویسندگان
چکیده
The use of ternary organic semiconducting blends is recognized as an effective strategy to boost the performance polymer solar cells (PSCs) by increasing photocurrent while minimizing voltage losses. Yet, scarcity suitable donors with a deep highest occupied molecular orbital (HOMO) level poses challenge in extending this systems based on two polymers. Here, we address synthesis new donor (PM7-Si), which akin well-known PM6 but has deeper HOMO level. PM7-Si utilized third component enhance best-in-class binary system PM6:BTP-eC9, leading simultaneous improvements efficiency (17.7%), open-circuit (0.864 V), and fill factor (77.6%). These decisively enhanced features are attributed efficient carrier transport, improved stacking order, morphology. Our results highlight promising toward high-performance PSCs.
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ژورنال
عنوان ژورنال: Chemistry of Materials
سال: 2021
ISSN: ['1520-5002', '0897-4756']
DOI: https://doi.org/10.1021/acs.chemmater.1c01433